Zeeman Splitting of Nuclear Quadrupole Resonance in Paradibromobenzene
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概要
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Zeeman patterns of the nuclear quadrupole resonance line of Br^<79> were studied with a single crystal of paradibromobenzene. The crystal contains two classes of molecules with equal positive and negative inclinations against the crystallographic b-axis. Changing the orientation of magnetic field in the plane perpendicular to the b-axis, the Zeeman patterns were measured. The asymmetry parameter of the coupling, η, was determined from the pattern at the magnetic field perpendicular to all carbon-brormine bonds. The result was η=0.12±0.01. The coupling constant, eQq, was measured as 535.19Mc at 14℃. If the asymmetry parameter is completely due to the resonance of a double bond structure in the carbon-bromine bond, the observed value gives 4.5 per cent double bond character.
- 社団法人日本物理学会の論文
- 1955-07-05
著者
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Kojima Shoji
Department Of Physics Tokyo University Of Education
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Kojima Shoji
Department Of Applied Physics Faculty Of Science Tokyo University Of Education
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Tsukada Kineo
Department Of Physics Tokyo University Of Education
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Hinaga Yasushi
Department Of Physics Tokyo University Of Education
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Kojima Shoji
Department Of Applied Physics Faculity Of Science Tokyo University Of Education
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KOJIMA Shoji
Department of Physics, Tokyo University of Education
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