Nuclear Quadrupole Resonances in Arsenic Tribromide and Arsenic Tri-iodide
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概要
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The pure quadrupole spectra of As^<76>, Br^<79> and Br^<81> in AsBr_3, and of I^<127> in AsI_3 have been studied by the method of superregenerative detection. The observed resonance frequencies yielded the following couplings: 127 Mc, 415 Mc and 1328 Mc for As^<75>, Br^<79> and I^<127> respectively. The spectrum of bromine in arsenic tribromide was a triplet. Above 90℃, the iodine in arsenic tri-iodide also showed a triplet, whereas below that temperature it had a single line. The asymmetry parameter on iodine was determined from the resonance frequencies. The result was 18.4% at the liquid air temperature and 14.5% at the room temperature. The low couplings and the high asymmetry of iodine in arsenic tri-iodide were interpreted by the mechanism of resonance switching of the bond.
- 社団法人日本物理学会の論文
- 1954-10-25
著者
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Ogawa Shizuko
Department Of Physics Tokyo University Of Education
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KOJIMA Shoji
Tokyo University of Education
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TSUKADA Kineo
Tokyo University of Education
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OGAWA Shizuko
Tokyo University of Education
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SHIMAUCHI Akira
Tokyo University of Education
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ABE Yoshihito
Tokyo University of Education
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Abe Yoshihito
Department Of Physics Tokyo University
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Tsukada Kineo
Department Of Physics Tokyo University Of Education
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Shimauchi Akira
Department Of Physics Tokyo University Of Education
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Shimauchi Akira
Tokyo Bunrika University
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Kojima Shoji
Tokyo Bunrika University
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KOJIMA Shoji
Department of Physics, Tokyo University of Education
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