First Total Synthesis of 4-Methylthio-3-butenyl Glucosinolate
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概要
- 論文の詳細を見る
The first total synthesis of 4-methylthio-3-butenyl glucosinolate (MTBG), a natural bioactive compound and a precursor of radish phototropism-regulating substances, was achieved from commercially available 1,4-butanediol. The glucosinolate framework was prepared by coupling of an oximyl chloride derivative and tetraacetyl thioglucose. A methylthio group was introduced to the framework by a Wittig reaction between triphenylphosphonium thiomethylmethylide and an aldehyde intermediate of glucosinolate. The synthetic route should facilitate preparation of various derivatives needed for probe synthesis based on MTBG.
- 社団法人 日本農芸化学会の論文
- 2009-03-23
著者
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Shigemori Hideyuki
Graduate School Of Life And Environmental Sciences University Of Tsukuba
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HASEGAWA Koji
Graduate School of Life and Environmental Sciences, University of Tsukuba
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YAMAZOE Sayumi
Graduate School of Life and Environmental Sciences, University of Tsukuba
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Yamazoe Sayumi
Graduate School Of Life And Environmental Sciences University Of Tsukuba
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Hasegawa Koji
Graduate School Of Life And Environmental Sciences University Of Tsukuba
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Hasegawa Koji
Graduate School Of Engineering Hokkaido University
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