Diffusion and Cluster Formation near NaCl Solution/Organic Solvent Interface in a Crystallization Process

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概要

• 論文の詳細を見る

• Molecular dynamics simulations have been performed for the design of operating conditions of liquid–liquid interfacial crystallization and clarifying the crystallization mechanism. It was found that solute ions were dehydrated with diffusion of the hydration ions from solution to organic phase. There were a significant difference of the dehydration behaviour between NaCl solution/1-butanol and /2-butanone. Aggregated ions or clusters were formed by the dehydration near the solution/organic solvent interface. The number of cluster generation near NaCl solution/2-butanone interface was larger than that in the 1-butanol system. This difference originates in the interfacial structure in the NaCl solution/the each organic solvent interface.

• 社団法人 化学工学会の論文
• 2009-07-01

著者

• Yamanaka Shinya

  Department of Stem Cell Biology, Institute for Frontier Medical Sciences, Kyoto University

• Shimosaka Atsuko

  Department of Chemical Engineering and Materials Science, Doshisha University

• Shirakawa Yoshiyuki

  Department of Chemical Engineering and Materials Science, Doshisha University

• Hidaka Jusuke

  Department of Chemical Engineering and Materials Science, Doshisha University

• Hidaka Jusuke

  Department Of Chemical Engineering And Materials Science Doshisha University

• Hidaka Jusuke

  Department Of Chemical Engineering And Material Science Faculty Of Science Engineering Doshisha Univ

• KITAYAMA Akira

  Department of Chemical Engineering and Materials Science, Doshisha University

• KADOTA Kazunori

  Department of Chemical Engineering and Materials Science, Doshisha University

• Yamanaka Shinya

  Department Of Chemical Engineering And Materials Science Doshisha University

• Shirakawa Yoshiyuki

  Department Of Chemical Engineering And Materials Science Doshisha University

• Shirakawa Y

  Osaka Univ. Osaka

• Shirakawa Yoshiyuki

  Department Of Materials Science And Processing Faculty Of Engineering Osaka University

• Hidaka J

  Department Of Chemical Engineering And Materials Science Doshisha University

• Kadota Kazunori

  Department Of Chemical Engineering And Materials Science Doshisha University

• Kitayama Akira

  Department Of Chemical Engineering And Materials Science Doshisha University

• Shimosaka A

  Department Of Chemical Engineering And Materials Science Doshisha University

• Shimosaka Atsuko

  Department Of Chemical Engineering And Materials Science Doshisha University

• Kadota Kazunori

  Department of Cardiovascular Medicine, Nephrology, and Neurology, Faculty of Medicine and Dialysis Unit, University Hospital of The Ryukyus and Okinawa General Health Maintenance Association

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