Correlation of Infinite Dilution Activity Coefficients of 1- and 2-Alkanols in Tetradecane and Hexadecane Using Modified ASOG
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概要
- 論文の詳細を見る
ASOG (Analytical Solution of Groups), which is widely applied to predict the liquid-phase activity coefficients of solutions, is extended to be capable to distinguish isomers. The Flory-Huggins (FH) part is examined by using the infinite dilution activity coefficient data of n-alkane binary mixtures and an empirical equation is proposed to modify the number of carbons contained in the n-alkanes. The concept of effective carbon number is adopted to apply the empirical equation to components other than n-alkanes. To evaluate the number of group, in the group interaction part, the contact probability is introduced, in which a steric hindrance factor is incorporated. The present model can give a good correlation for the infinite dilution activity coefficients of 1- and 2-alkanols in tetradecane and hexadecane.
- 社団法人 化学工学会の論文
著者
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福地 賢治
宇部工業高等専門学校物質工学科専攻科物質工学専攻主任
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WATANABE Toru
Department of Medical Oncology, National Cancer Center Hospital
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ARAI Yasuhiko
Department of Chemical Engineering, Faculty of Engineering, Kyushu University
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Arai Y
Department Of Chemical Engineering Faculty Of Engineering Kyushu University
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Arai Y
Department Of Chemical Engineering Graduate School Of Engineering Kyushu University
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Arai Yasuhiko
Department Of Chemical Engineering Kyushu University
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Fukuchi Kenji
Department Of Chemical And Biological Engineering Ube National College Of Technology
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YONEZAWA Setsuko
Department of Chemical Engineering, Graduate School of Engineering, Kyushu University
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Watanabe Toru
Department Of Cardiology Kinki University School Of Medicine
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Watanabe Toru
Department Of Chemical Science And Engineering Ariake National College Of Technology
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Yonezawa Setsuko
Department Of Chemical Engineering Faculty Of Engineering Kyushu University
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Arai Yasuhiko
Department Of Chemical Engineering
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Watanabe Toru
Department Of Aquatic Biosciences Tokyo University Of Fisheries
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ARAI YASUHIKO
Department of Chemical Engineeering, Tohoku University
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