Synthesis and Polymerization of a para-Disubstituted T8-caged Hexaisobutyl-POSS Monomer
スポンサーリンク
概要
- 論文の詳細を見る
A para-substituted bis(3-aminopropyl)hexaisobutyl-polyhedral oligomeric silsesquioxane (POSS) was successfully synthesized via a selective corner-opening reaction of 3-aminopropylheptaisobutyl-POSS and a subsequent corner-capping reaction. The selectivity of the corner-opening reaction was studied by density functional theory calculations. Polymerization of the POSS monomer with pyromellitic dianhydride resulted in a yellow, self-standing film.
- 公益社団法人 日本化学会の論文
著者
-
Naka Kensuke
Department Of Chemistry And Materials Technology Graduate School Of Science And Technology Kyoto Ins
-
Irie Yasuyuki
Department Of Pharmacology Osaka University School Of Medicine
-
Tanaka Kazuyoshi
Department Of Biofunctional Informatics Graduate School Of Health Care Sciences Tokyo Medical And De
-
Fueno Hiroyuki
Department Of Molecular Engineering Graduate School Of Engineering Kyoto University
-
NAKA Kensuke
Department of Chemistry and Materials Technology, Graduate School of Science and Technology, Kyoto Institute of Technology
-
TANAKA Kazuyoshi
Department of Molecular Engineering, Graduate School of Engineering, Kyoto University
-
Maegawa Takayuki
Department of Chemistry and Materials Technology, Graduate School of Science and Technology, Kyoto Institute of Technology
関連論文
- Ultrasonic anisotropy measured in 2-dimensional echocardiograms in vitro and verified by histology
- Synthesis and Structures of Highly Conducting Charge-Transfer Salts of Selenium Containing TTM-TTP Derivatives
- Synthesis and Structures of Neutral Crystals and Charge-Transfer Salts of Selenium Containing TMET-TTP Derivatives
- Preparation and Characterization of Novel Aromatic-inserted Tris-fused Tetrathiafulvalenes
- Microscopic Investigation of a New Two-Component Organic Conductor with Itinerant and Localized Spins : (CHTM-TTP)_2TCNQ
- Dimerization Effect on the Physical Properties in New One-Dimensional Organic Conductors: (ChTM-TTP)_2AuBr_2, (ChTM-TTP)_2GaCl_4, and (ChTM-TTP)ReO_4
- A Novel Organic Conductor with Two-Dimensional Molecular Array by the "Edge-to-Edge" Donor Interaction
- Marginal Paramagnetic State of a One-Dimensional Half-Filled Alternating Chain in (TTM-TTP) AuI_2 : Condensed Matter: Electronic Properties, etc.
- A Novel Organic Conductor with Three-Dimensional Molecular Array: (TM-TPDS)_2AsF_6
- ESR Investigation of Organic Conductors (DTM-TTP)(TCNQ)(TCE) and (TMET-TTP)_2(TCNQ) : Condensed Matter: Electronic Properties, etc.
- Raman Investigation of the One-Dimensional Organic Conductor with a Half-Filled Band,(TTM-TTP) I_3
- Structures and Properties of (TMEO-ST-TTP)_2AsF_6
- Novel One-Dimensinal Organic Conductor Based On Selenium-Containing Bis-Fused Tetrathiafulvalene Derivative, (TSM-TTP)(I_3)5/3
- Structure and Properties of (DTM-TTP)(TCNQ)(TCE) and the Related Complex
- A carbonate controlled-addition method for size-controlled calcium carbonate spheres by carboxylic acid-terminated poly(amidoamine) dendrimers
- The Sea Urchin-shaped CaCO_3 via Template Mineralization on Surface-functionalized Vaterite Particles by Tiopronin-protected Gold Nanoparticles
- Inhibition by Naloxone of Promoter Activity of the Neurofilament Gene in SK-N-SH Cells
- Amphiphilic Tetrathiafulvalene Derivative : Charge-Transfer Complexation Behavior in Solutions
- Intramolecular Charge-Transfer Polymers between Dithiafulvene and Pyridinium Units : Conjugative Effect through Saturated Polymethylene Chains
- Self-Complexation of a Poly-Conjugated Donor Molecule with a Cyclic Acceptor
- Linearly Extended π-Conjugated Dithiafulvene Polymer Formed Soluble Charge-Transfer Complex with 7,7,8,8-Tetracyanoquinodimethane
- Hydrophobic Scale : a Second Parameter to Elucidating Various Specific Ligand-Protein Interactions
- A New Application of Sequence Fourier Analysis to Specific Ligand-Protein Interactions
- Analysis of the Peptides (Prp106-126, MSI-78A, and Oxaldie 1) with the Same Biological Activity by Discrete Fourier Transform: Toward a Selection Rule in Ligand-Receptor Interaction
- Ab lnitio CASSCF Study on Doublet and Quartet States of 1,3,5-Tris(methylene)benzene and 1,3,5-Benzenetriamine Trication
- Electron Spin Resonance of the Quartet State of 1,3,5-Tris(diphenylamino)benzene
- Novel Aprotic Polar Polymers V. Synthesis of Poly(HMPA) by Ring-Opening Polymerization
- Novel Aprotic Polar Polymers IV. Synthesis of Poly[(N-bis(dimethylamino)phosphorylethylenimine] as a Polymer Homolog of Hexamethylphosphoramide
- Improving Proton Relaxivity of Dendritic MRI Contrast Agents by Rigid Silsesquioxane Core
- Synthesis of Helical Polymers with a Pentasilane Core
- Effect of Anionic Polyamidoamine Dendrimers on the Crystallization of Calcium Carbonate by Delayed Addition Method
- Structures and Electrical Properties of β- and θ-(BTM-TTP)_2SbF_6
- Synthesis of Electron-Donating Polymer Having Vinylogous TTF in the Main Chain
- Synthesis of Soluble Complexan Polymers in Organic Solvents for Using as a Polymer-Chelate Precursor to YBa_2Cu_3O_ Thin Films
- Sensing of Poly(styrenesulfonate)s by Polymeric Membrane Electrodes Based on Liquid Anion-Exchangers
- Adsorption of Enzymes at Silica-Gel with Amphiphilic Block Copolymers
- Aggregates of Amphiphilic Block Copolymers Derived from Poly [(N - acylimino)ethylene]s and Their Complexes with Lipase in Water
- Adsorption of Amphiphilic Block Copolymer-Catalase Aggregate at Silica-Gel
- Enzyme Electrode for Hydrogen Peroxide Using a New Enzyme-Immobilization "Polymer-Enzyme Aggregate"
- Two-Dimensional Band Structure of Organic Metals (BDT-TTP)_2X (X=SbF_6,AsF_6)Studied by Polarized Reflection Spectroscopy
- Synthesis and Characterization of New Side-Chain Liquid Crystalline Polyoxazolines
- Effect of Molecular Weights of Poly(acrylic acid) on Crystallization of Calcium Carbonate by the Delayed Addition Method
- Thermoresponsive Organic - Inorganic Polymer Hybrids from Poly(N - isopropylacrylamide)
- Reversible Formation of Interpenetrating Polymer Network Structure in Organic-Inorganic Polymer Hybrids
- Theoretical Study of Lithium-Doped Polycyclic Aromatic Hydrocarbons
- Magnetic Properties of 1,3,5-Tris[bis(p-methoxyphenyl)amino]benzene Cation Radicals
- Control Crystallization of Calcium Carbonate in Aqueous Solution with In-Situ Radical Polymerization of Sodium Acrylate as a Latent Inductor for Crystal Nucleation and Growth
- pH Responsive Aggregation of Imidazolium Cations-Modified Gold Nanoparticles with Poly(acrylic acid) in Aqueous Solution
- Nanometer-Scale Lithography on the Oligosilane Langmuir-Blodgett Film
- Effect of Anionic 4.5-Generation Polyamidoamine Dendrimer on the Formation of Calcium Carbonate Polymorphs
- Synthesis of Poly (Cyclodiborazane)s by Hydroboration Polymerization Using Mesitylborane
- Deep Impurity Centers in CdS Single Crystals Studied by Spectral Analysis of Deep Level Transient Spectroscopy
- Self-Assembly of Gold Nanoparticles Utilizing a Charge-Transfer Interaction between Carbazolyl and Dinitrophenyl Units
- Self-organized Wire-like Aggregates of Palladium Nanoparticles with Poly(amidoamine)dendrimer
- Preparation of Gold Nanoparticles Protected by a Cubic Silsesquioxane and Their Monolayer Formation on a Glass Substrate
- Self-organized Nanocomposites of Functionalized Gold Nanoparticles with Octa(3-aminopropyl)octasilsesquioxane
- A Simple In Situ Hydrogen Bond Interaction to Homogeneous Dispersion of Gold Nanoparticles in SiO_2 Matrix Using Dendrimer as Template
- Synthesis and Properties of New Tetrathiapentalene Donors Composed of Vinylogous TTFs
- Synthesis of Fullerene-Porphyrin Complex
- Conducting Salts Composed of Selenium Analogues of TMET-TTP
- Through-Bond and Through-Space Interactions of Organic Radicals Coupled by m-Phenylene
- Synthesis of Diazafluorene-functionalized TTF Donors
- Occurrence and lithofacies of shungite : early Proterozoic carbon-rich rocks from Karelia, northwestern Russia
- Structures and Electrical Properties of (BTM-TS-TTP)_4PF_6
- Effect of Pellet Size on Discharge Characteristics of Latent Heat Storage Columns Packed With Cross-Linked Polymer Pellets
- Synthesis of Poly(N, N-dimethylacrylamide)/Silica Gel Polymer Hybrids by In Situ Polymerization Method
- Synthesis and low-temperature dehydrating imidation polymerization of 1,4-dihydro-1,4-diarsininetetracarboxylic acid dianhydride
- Effect of solvent polarity on enzymatic function of poly [(N-acylimino)ethylene] modified lipase
- Preparation of Soluble Poly(azomethine)s Having the β-Diketonate Metal Complex in the Main Chain
- Synthesis and Optical Properties of Soluble Isoxazole-Containing Poly(p-phenylene)-Related Polymer
- Synthesis of Polymers Containing Group 15 Elements via Bismetallation of Acetylenic Compounds
- Density Functional Theory Studies on Chemical Functionalization of Single-Walled Carbon Nanotubes by Bingel Reaction
- Synthesis of first- and second-generation imidazole-terminated POSS-core dendrimers and their pH responsive and coordination properties
- Synthesis of calcium carbonate particles with carboxylic-terminated hyperbranched poly(amidoamine) and their surface modification
- Syntheses and properties of star- and dumbbell-shaped POSS derivatives containing isobutyl groups
- Enantioselective Extraction of Di-O-benzoyltartrate Anion by Ion-Pair Extractant Having Binaphthyl-Unit.
- Detection of Calpastatin and a Trypsin Inhibitor in Carp Muscle
- Occurrence and lithofacies of shungite: early Proterozoic carbon-rich rocks from Karelia, northwestern Russia
- An Application of the 0s-Function to Molecular Systems of H2+ and H2
- A Study of the Upper and Lower Bounds of the Second-order Perturbation Energy
- The electronic states of (SN)x and (SCH)x polymers.
- Polarographic Investigation of Oxidation Reaction of Vanadium(II) by Nitrate Ion
- Inverse Relationship of Reorganization Energy to The Number of π Electrons from Perspective of Vibronic Coupling Density
- A theoretical study on biradicals. I. Theoretical characteristics of biradicals.
- A stereoselective rule for the cross-bicyclization in linear conjugated polyenes.
- Long-range Interaction between a Hydrogen Atom and a Hydride Ion
- CNDO/2 Calculations on the Configurations of the Ion-molecule Complexes. The NH4+–CH4, H3O+–CH4 and NH4+–H2 Systems
- Synthesis and Polymerization of a para-Disubstituted T8-caged Hexaisobutyl-POSS Monomer