A theoretical study on biradicals. I. Theoretical characteristics of biradicals.
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概要
- 論文の詳細を見る
An interpretation is given on the characteristics of biradicaloids, such as the bonding, polar, and biradical characters of singlet biradicals. Systematization of the reactivity of singlet and triplet biradicals is based on the principle that 1) deformation takes place in the direction of bonding in singlet biradicals, and 2) deformation or bond formation occurs to separate unpaired-electrons from each other in triplet biradicals. Combination of the two principles is applied to the theory of orientation and stereoselection in excited-state reactions.
- 公益社団法人 日本化学会の論文
著者
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Fukui Kenichi
Department Of Chemistry Graduate School Of Science The University Of Tokyo
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Tanaka Kazuyoshi
Department Of Biofunctional Informatics Graduate School Of Health Care Sciences Tokyo Medical And De
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Tanaka Kazuyoshi
Department of Hydrocarbon Chemistry, Faculty of Engineering, Kyoto University
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