Electrochemical Oxidation of L-Prolinol Derivative Protected with 1-Alkoxy-2,2,2-trifluoroethyl Group
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概要
- 論文の詳細を見る
1-Alkoxy-2,2,2-trifluoroethyl group was found to be a new protecting group for electrochemical oxidation of L-prolinol. The result is a first example for the introduction of a nucleophile to α-position of L-prolinol without a loss of the optical activity through an iminium ion intermediate. This exploited method is complementary for methods in which an electrophile is introduced to the α-position of L-proline derivative through a carbanion intermediate.
- 公益社団法人 電気化学会の論文
著者
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Demizu Yosuke
Faculty Of Pharmaceutical Sciences At Kagawa Campus Tokushima Bunri University
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ISHIDA Yukihiro
Faculty of Engineering, Saitama University
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MAKI Toshihide
Faculty of Pharmaceutical Sciences, Graduate School of Biomedical Sciences, Nagasaki University
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DEMIZU Yosuke
Faculty of Pharmaceutical Sciences, Graduate School of Biomedical Sciences, Nagasaki University
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ONOMURA Osamu
Faculty of Pharmaceutical Sciences, Graduate School of Biomedical Sciences, Nagasaki University
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MINATO Daishirou
Faculty of Pharmaceutical Sciences, Graduate School of Biomedical Sciences, Nagasaki University
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MATSUMURA Yoshihiro
Faculty of Pharmaceutical Sciences, Graduate School of Biomedical Sciences, Nagasaki University
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ISHIDA Yukihiro
Faculty of Pharmaceutical Sciences, Graduate School of Biomedical Sciences, Nagasaki University
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- Electrochemical Oxidation of L-Prolinol Derivative Protected with 1-Alkoxy-2,2,2-trifluoroethyl Group