酸触媒を用いる過クエン酸の合成および電気化学的検出
スポンサーリンク
概要
- 論文の詳細を見る
Peroxycitric acid (PCA) was successfully synthesized for the first time as an equilibrium mixture with citric acid and hydrogen peroxide using sulfuric acid (homogeneous) and Nafion (heterogeneous) catalysts. The formation of PCA in the equilibrium mixture was detected by the potentiometric measurement based on the triiodide/iodide redox couple potential buffer and the concentration of PCA was determined from the obtained potential change. The equilibrium % yield of PCA was found to largely depend on the concentration and the nature of catalysts. The peculiar roles of the heterogeneous and homogeneous catalysts in the formation of PCA were discussed briefly.
- 公益社団法人 電気化学会の論文
著者
-
Ferdousi Begum
Department Of Electronic Chemistry Interdisciplinary Graduate School Of Science And Engineering Toky
-
Islam Md.
Department Of Advanced Materials Science And Engineering Yamaguchi University
-
Awad Mohamed
Department Of Chemistry Faculty Of Science Tanta University
-
Kitamura Fusao
Department Of Electronic Chemistry Interdisciplinary Graduate School Of Science And Engineering Toky
-
Ohsaka Takeo
Department Of Applied Chemistry Faculty Of Technology Tokyo University Of Agriculture And Technology
-
Okajima Takeyoshi
Department Of Electronic Chemistry Interdisciplinary Graduate School Of Science And Engineering Toky
-
AWAD Mohamed
Department of Electronic Chemistry, Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology
関連論文
- Mineralogy of Soils from Different Agroecological Regions of Bangladesh : Region 2 - Active tista Floodplain, Region 4 - Karatoya - Bangali Floodplain and Region 7 - Active Brahmaputra - Jamuna Floodplain
- Some Chemical Properties of Soils from Two Agroecological Regions of Bangladesh : Region 5 : Lower Atrai Basin and Region 6 : Lower Purnabhaba Floodplain
- INVESTIGATION OF COMPONENTS INVOLVED IN CYCLIC ELECTRON TRANSPORT BY MEANS OF MUTAGENESIS
- 酸触媒を用いる過クエン酸の合成および電気化学的検出
- 短形波ボルタンメトリーによる過酢酸と過酸化水素の同時定量
- キノリン溶液中水銀被覆金電極でのO2/O2レドックス反応における電気化学振動現象
- 酸性溶液中における多結晶金電極表面上でのピリジンカルボン酸の吸着挙動の赤外反射分光法による研究
- サンドイッチ構造のビス(フタロシアニナト)ランタニド錯体の電気化学及び分光電気化学による研究
- Solvatochromic Linear Solvation Energy Relationships for Solubility of O_2 in Various Solvents
- 溶液のリ-クのある微小電極
- New Oscillatory Phenomena in the Redox Reaction of O_2/O_2^-Couple on a Hanging Mercury Drop Electrode in Acetone Media
- Solvatochromic Linear Solvation Energy Relationships for Solubility of O_2 in Various Media Containing Tetraethylammonium Perchlorate
- Electrocatalytic Reduction of Dioxygen in the Presence of N, N' -Dipentyl Viologen
- Enhanced Hydrogen Adsorption/Desorption Characteristic of Ta_2O_5-coated Pt Electrode Prepared by Electrodeposition of Ta and the Subsequent Calcination
- 脂溶性アスコルビン酸存在下における電解生成ス-パ-オキシドイオンによるウミホタルルシフェリン類縁体の化学発光
- Electrocatalysis of a Series of N, N'-Dialkyl Viologens for Reduction of Dioxygen : Effect of Alkyl Chain Length
- RETRIEVAL OF CHLOROPHYLL a CONCENTRATION IN CASE 2 WATER BY USING SeaWIFS AND FIELD SPECTRORADIOMETER DATA
- Selective Formation of Alkoxo-bridged Titanium(IV) Polynuclear Complexes with Polyaminopolycarboxylate : First Titanium(IV) Octanuclear Complex Containing Cubic-type {Ti_4(μ-oxo)_4}_2(μ-alkoxo)_4 Core
- Chaotic dynamics of a behavior-based miniature mobile robot : effects of environment and control structure
- A new algorithm to design compact two-hidden-layer artificial neural networks
- Cytotoxic Evaluation of Ag@TiO_2 Core-Shell Composite Nanoclusters against Cancer Cells
- Enhanced Photocatalytic Cytotoxic Activity of Au@TiO_2 Nanopellets against Human Epithelial Carcinoma (HeLa) Cells
- Antioxidant, Free Radical-Scavenging, and NF-κB-Inhibitory Activities of Phytosteryl Ferulates : Structure-Activity Studies
- Antioxidant, Free Radical–Scavenging, and NF-κB–inhibitory Activities of Phytosteryl Ferulates: Structure–Activity Studies
- Preparation and Gas Permeation Properties of Composite Carbon Molecular Sieve Membranes Derived from Polyimides with Thermally Decomposable Sulfonic Acid Salt and/or Hexafluoroisopropylidene Group
- Antimutagenicity of Mono-, Di-, and Tricaffeoylquinic Acid Derivatives Isolated from Sweetpotato (Ipomoea batatas L.) Leaf(Food & Nutrition Science)
- Characteristics of Precipitation Systems Analyzed from Radar Data over Bangladesh
- Application of a Method to Estimate Rainfall in Bangladesh Using GMS-5 Data
- 白金(111)単結晶電極におけるトリス(1,10-フェナントロリン)コバルト(II)/(III)のレドックス電極反応速度に与えるアニオンの効果
- Spatial and Temporal Variations of Precipitation in and around Bangladesh
- 新規大環状ニッケル錯体の自己組織化単分子膜の電気化学的挙動及び過酸化水素の電極触媒酸化
- Electrochemical and Spectral Studies on Nikel(II/III) Complexes with Novel 14-Membered Hexaaza Macrocycle Functionalized with Propenyl Groups
- Anthocyanin Compositions in Sweetpotato (Ipomoea batatas L.) Leaves(Food & Nutrition Science)
- Potentiation by Higenamine of the Aconitine-Induced Positive Chronotropic Effect in Isolated Right Atria of Mice : The Effects of Cholera Toxin, Forskolin and Pertussis Toxin
- MINERALOGY OF SOILS FROM DIFFERENT AGROECOLOGICAL REGIONS OF BANGLADESH : REGION 9-OLD BRAHMAPUTRA FLOODPLAIN
- Realization of n-type and p-type Si-Microprobe Array Using In-Situ Doping with Selective Vapor-Liquid-Solid (VLS) Growth Method
- チオフェノ-ル修飾金電極による水溶液中でのス-パ-オキシドイオンの電解生成〔英文〕 (バイオエレクトロケミストリ-の新展開)
- Simultaneous Spectrophotometric Determination of Ozone and Hydrogen Peroxide
- Superior Electrocatalysis of Spin-coated Titanium Oxide Electrodes for the Electrochemical Ozone Production
- Synthesis of Gerfelin and Related Analogous Compounds
- Light-Dependent Intracellular Positioning of Mitochondria in Arabidopsis thaliana Mesophyll Cells
- Experimental Study of the Effect of Different Crack Widths on CO2 ingress into Concrete with Repair Patch (特集2 持続可能な都市システムの構築をめざして(ICUS))
- Genomic organization, alternative splicing, and multiple regulatory regions of the zebrafish fgf8 gene
- MINERALOGY OF SOILS FROM DIFFERENT AGROECOLOGICAL REGIONS OF BANGLADESH : REGION 1-OLD HIMALAYAN PIEDMONT PLAIN
- Acetylcholine-Induced Biphasic Effect on the Maximum Upstroke Velocity of Action Potential in Mouse Right Atria : Interaction With β-Adrenergic Signaling Cascade
- Simplified Heat Transfer Model of Horizontal U-Tube (HUT) System
- Mechanism of Water Attacking on Brooker's Merocyanine Dye and Its Effect on the Molecular and Electronic Structures : Theoretical Study
- Protein Tyrosine Phosphatase 1B and α-Glucosidase Inhibitory Phlorotannins from Edible Brown Algae, Ecklonia stolonifera and Eisenia bicyclis
- Magnetic Resonance-visible Coating for Endovascular Device Visualization : Gadolinium(III)-Diethylenetriaminepentaacetic Acid-based Insoluble Polymer Coating
- シスタミン修飾電極によるアスコルビン酸とドーパミンの同時検出
- In Situ Electrochemical Quartz Crystal Microbalance Measurement of Au Deposition and Dissolution in Room-Temperature Ionic Liquid Containing Chloride Ion
- O_2 Gas Sensor Using Supported Hydrophobic Room-temperature Ionic Liquid Membrane-coated electrode
- 水溶液中におけるポリアニリン修飾電極を用いたスーパーオキシドイオンの電解生成
- Simultaneous Electroanalysis of Ascorbic Acid, Dihydroxyphenylacetic Acid, Homovanillic Acid and Uric Acid Using Gold Electrode Modified with Cationic Self-Assembled Monolayers
- Catalytic Electrooxidation of Formaldehyde at Ta_2O_5-modified Pt Electrodes
- Dual Catalysts System Based on Nano-manganese Oxide and Multiwall Carbon Nanotube for Four-electron Oxygen Reduction
- Probing Absorption of Deuterium into Palladium Cathodes During D_2O Electrolysis with an In Situ Electrochemical Microbalance Technique
- Characteristics of a Field-Effect Transistor Fabricated with Electropolymerized Thin Film : Semiconductors and Semiconductor Devices
- Spectroelectrochemical Detection of an Intermediate in the Alcohol Oxidation Process with a Nitroxyl Radical
- Observation of Intermolecular Charge-Transfer Spectra for propyl Viologen Dihalides in a Series of Polyether Media
- Horizontal U-Tube Road Heating System using Tunnel Ground Heat
- Increased Hepatic Nicotinamide N-Methyltransferase Activity as a Marker of Cancer Cachexia in Mice Bearing Colon 26 Adenocarcinoma
- Reaction of Amino Acids in a Supercritical Water-Flow Reactor Simulating Submarine Hydrothermal Systems
- P-436 SYNTHESIS OF (-)-MELLEIN, (+)-RAMULOSIN AND RELATED NATURAL COMPOUNDS
- Spectroelectrochemical Study of the Reversible Adduct Formation of Bis(phthalocyaninato)neodymate(III) Complex with CO_2 in a DMF Solution
- Synergistic Cell Killing by Magnetic and Photoirradiation Effects of Neck-structured α-Fe_2O_3 against Cancer (HeLa) Cells
- Protein Tyrosine Phosphatase 1B and α-Glucosidase Inhibitory Phlorotannins from Edible Brown Algae, Ecklonia stolonifera and Eisenia bicyclis
- One-step and large scale synthesis of non-metal doped TiO_2 submicrospheres and their photocatalytic activity
- Realization of In Situ Doped n-Type and p-Type Si-Microprobe Array by Selective Vapor-Liquid-Solid (VLS) Growth Method
- Allelopathic potential of methanol extracts of Bangladeshi rice cultivars
- Gd-DTPA-based MR-visible Polymer for Direct Visualization of Interventional Devices
- Khatmiamycin, a motility inhibitor and zoosporicide against the grapevine downy mildew pathogen Plasmopara viticola from Streptomyces sp. ANK313
- 酸触媒を用いる過クエン酸の合成および電気化学的検出
- The Aerodynamic Performance of a Horizontal-Axis Wind Turbine Calculated by Strip Theory and Cascade Theory
- Zero Energy Cool Chamber for Extending the Shelf-Life of Tomato and Eggplant
- Promising antidiabetic potential of fucoxanthin isolated from the edible brown algae Eisenia bicyclis and Undaria pinnatifida
- Electrode kinetics of metal complexes confined in perfluoro polycarboxylate and polysulfonate coatings on graphite electrodes.
- Micro-Raman Characterization of Starting Material for Traveling Liquidus Zone Growth Method
- Electrocatalysis by Nanoparticles: Fabrication and Electrochemical Applications of Tailor-Designed Nanoparticles-Based Electrocatalysts
- Electrochemical calorimetry of D2O electrolysis using a palladium cathode. An undivided, open cell system.
- Electrode kinetics of viologen polymers attached on graphite surfaces.
- Electrode kinetics of the redox couples of Co(III/II) complexes with ethylenediamine-N-acetate, iminodiacetate, and diethylenetriamine.
- Normal pulse polarographic study of the electrode reaction of copper(II) complexes with ethylenediaminetetraacetic acid(EDTA) and N-(2-hydroxyethyl)ethylenediamine-N,N',N'-triacetic acid(HEDTA).
- Diabetes Mellitus-Induced Enhancement of Prostaglandin F2.ALPHA.-Responses Is Inhibited by Lipoxygenase- but Not Cyclooxygenase-Inhibitors in Mesenteric Veins and Arteries of Mouse and Rat.
- Effects of supporting electrolyte and pH on charge transport within electropolymerized poly(o-phenylenediamine) films deposited on graphite electrodes.
- Accelerated Electron-Transfer Reaction of the O2/O2− Redox Couple on Multi-Walled Carbon Nanotubes—Modified Edge-Plane Pyrolytic Graphite Electrode in Room-Temperature Ionic Liquids
- Charge-transfer rates in thin polyelectrolyte films incorporating a redox molecule with two separate electroactive centers having different redox potentials. An Alizarine Red S-cationic perfluoropolymer film system.
- Phosphate deficiency signaling pathway is a target of arsenate and phosphate transporter OsPT1 is involved in As accumulation in shoots of rice(Plant nutrition)
- Double potential step chronoamperometry for reversible follow-up chemical reactions. Application to the aquation kinetics of bis(ethylenediaminemonoacetato)cobalt(II).
- Electroreduced Tantalum Pentaoxide for Hydrogen Evolution Reaction
- 1P181 Microscopic observation of chemotactic behaviors of Leptospira(12.Cell biology,Poster,The 51st Annual Meeting of the Biophysical Society of Japan)