Effects of Carbon Dioxide on the Performance of Anion-Exchange Membrane Fuel Cells
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概要
- 論文の詳細を見る
The effects of CO2 on the performance of an anion-exchange membrane fuel cell were investigated using a three-electrode single cell equipped with a reference electrode. Though the membrane resistance decreased at high current densities in the presence of CO2 via the self-purging mechanism, the cell voltage was significantly lower than that for pure O2 especially at low current densities even at a very low CO2 concentration of 100 ppm. The overpotential at the cathode was hardly changed by the presence of CO2, while that at the anode significantly increased in the presence of CO2. It was concluded that carbonate/bicarbonate ions accumulated at the anode during operation, and reduces the ionic conductivity and the pH in the anode catalyst layer, which results in a high overpotential at the anode.
- 公益社団法人 電気化学会の論文
著者
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Inaba Minoru
Department Of Energy And Hydrocarbon Chemistry Graduate School Of Engineering Kyoto University
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SAITO Morihiro
Department of Chemistry, Rikkyo University
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TASAKA Akimasa
Department of Molecular Chemistry and Biochemistry, Faculty of Science and Engineering, Doshisha University
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FUKUTA Kenji
Corporate Development Department, Tokuyama Corporation
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MATSUI Yu
Department of Molecular Chemistry and Biochemistry, Faculty of Science and Engineering, Doshisha University
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WATANABE Shin
Corporate Development Department, Tokuyama Corporation
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YANAGI Hiroyuki
Corporate Development Department, Tokuyama Corporation
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INABA Minoru
Department of Applied Chemistry, Graduate School of Engineering, Doshisha University
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