The total synthesis of hydroxyisochamaecynone and its stereochemical assignment.

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概要

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• The structure of an acetylenic nor-sesquiterpene, hydroxyisochamaecynone, was determined to be 4α-hydroxy-5β<I>H</I>-13-noreudesm-1-en-11-yn-3-one (Ib) by means of the stereoselective total syntheses of two possible stereoisomers, Ib and 4β-hydroxy-5β<I>H</I>-13-noreudesm-1-en-11-yn-3-one.

• 公益社団法人 日本化学会の論文

著者

• Ando Masayoshi

  Department of Applied Chemistry, Niigata University

• Takase Kahei

  Department Of Chemistry Faculty Of Science Tohoku University

• Asao Toyonobu

  Department of Chemistry Faculty of Science Tohoku University

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