The copper(I) iodide-assisted reaction of nonactivated aryl iodides with some alkali metal pseudohalides.
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概要
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Copper(I) iodide dissolves into warm hexamethylphosphoric triamide to give a black solution, in which polymethylated iodobenzenes undergo nucleophilic attack by azide and selenocyanate ions, giving the corresponding aryl azides and selenocyanates in low to good yields. In the absence of copper(I) salt, however, the reaction does not take place. Cyanide, cyanate, thiocyanate, and fluoride ions bring about a decoloration of the reaction mixture and no displacement reactions ensue, while the tellurocyanate ion affords the corresponding aryl cyanides while liberating elemental tellurium.
- 公益社団法人 日本化学会の論文
著者
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Miyoshi Keiko
Department Of Biochemistry School Of Dentistry The University Of Tokushima
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Suzuki Hitomi
Deparment Of Chemistry School Of Science Kwansei Gakuin University
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Miyoshi Keiko
Department of Chemistry, Faculty of Science, Ehime University
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Shinoda Misao
Department of Industrial Chemistry, Faculty of Engineering, Toyama University
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