Reaction of Tetrachloroxylenes with Fuming Nitric Acid. Side-chain Nitrooxylation and Quinol Nitrate Formation
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概要
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Direct action of fuming nitric acid upon tetrachloro-<I>o</I>- and -<I>m</I>-xylenes at room temperatur led to the formation of 3,5,6-trichloro-1,2-dimethyl-4-oxocyclohexa-2,5-dienyl nitrate and 2,5,6-trichloro-1,3-dimethyl-4-oxocyclohexa-2,5-dienyl nitrate, respectively, as the major products. In contrast, tetrachloro-<I>p</I>-xylene was simply converted into 2,3,5,6-tetrachloro-4-methylbenzyl nitrate. Plausible reaction sequences as well as criteria as a basis for predicting the propensity of polysubstituted alkylaromatics towards unusual nitration have been discussed.
- 公益社団法人 日本化学会の論文
著者
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Suzuki Hitomi
Deparment Of Chemistry School Of Science Kwansei Gakuin University
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MARUYAMA SHIGERU
Department of Pediatrics, School of Medicine, Kanazawa University
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Ishizaki Katsuro
Department of Chemistry, Faculty of Science, Hiroshima Uninersity
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Hanafusa Terukiyo
Department of Chemistry, Faculty of Science, Hiroshima University
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Hanafusa Terukiyo
Department of Chemistry, Faculty of Science, Hiroshima Uninersity
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