Oxidation of nitrotoluenes with electro-generated superoxide ion.
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概要
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The oxidation of <I>o</I>-, <I>m</I>-, and <I>p</I>-nitrotoluenes with electro-generated superoxide ion in dimethylformamide was studied using cyclic voltammetry and controlled potential macro-electrolysis. The electrochemical reduction of oxygen in the presence of <I>o</I>- and <I>p</I>-nitrotoluenes yielded the corresponding carboxylic acids because the methyl groups in these derivatives are activated by the nitro group. An intermediate in these oxidations should be the corresponding nitrobenzaldehyde. The reaction mechanism is discussed.
- 公益社団法人 日本化学会の論文
著者
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Osa Tetsuo
Pharmaceutical Institute Tohoku University
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Lund Henning
Pharmaceutical Institute, Tohoku University
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Sagae Hiromitsu
Pharmaceutical Institute, Tohoku University
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Fujihira Masamichi
Pharmaceutical Institute, Tohoku University
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