Catalytic and electrocatalytic hydrogenation of benzylideneazlactone and benzylidenehydantoin.
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概要
- 論文の詳細を見る
The electrocatalytic hydrogenatoin of benzylideneazlactone and 5-benzylidenehydantoin with Raney-nickel cathode proceeded smoothly to afford <I>N</I>-acetylphenylalanine and 5-benzylhydantoin, respectively. In addition, refluxing the electrolyte solution after the electrolysis finally yielded phenylalanine with satisfactory chemical yields and current efficiencies. This electrocatalytic process showed slightly higher reactivity than the ordinary catalytic hydrogenation.
- 公益社団法人 日本化学会の論文
著者
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Osa Tetsuo
Pharmaceutical Institute Tohoku University
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TAKAHASHI HIROKO
Pharmaceutical Research Center, Meiji Seika Kaisha, Ltd.
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Matsue Tomokazu
Pharmaceutical Institute, Tohoku University
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Yamada Tsukasa
Pharmaceutical Institute, Tohoku University
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Takahashi Hiroko
Pharmaceutical Institute, Tohoku University
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