Stereochemical behavior of 1-methoxycyclopropyl radical in Hunsdiecker reaction.
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概要
- 論文の詳細を見る
The Hunsdiecker reaction of Ag (<I>E</I>)- and (<I>Z</I>)-2,2-dichloro-1-methoxy-3-methylcyclopropanecarboxylates with bromine in CCl<SUB>4</SUB> at 0 and 77 °C occurs with substantial inversion of configuration, suggesting that the 1-methoxycyclopropyl radical is configurationally less stable than the 1-fluorocyclopropyl or the 1-methoxyvinyl radical.
- 公益社団法人 日本化学会の論文
著者
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Matsumoto Masahiro
Department Of Clinical Physiology Tokyo Metropolitan Institute Of Gerontology
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Ando Teiichi
Department Of Mechanical Industrial And Manufacturing Engineering Northeastern University
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Yamashita Akira
Department Of Anatomy Hamamatsu Medical University
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Ishihara Takashi
Department Of Applied Physics Nagoya University
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Matsumoto Masahiro
Department of Industrial Chemistry, Faculty of Engineering, Kyoto University
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