Substituent effect on a photo-Smiles rearrangement by laser photolysis.
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概要
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The photo-Smiles rearrangement was studied for two homologues of <I>N</I>-[2-(4-nitrophenoxy)ethyl]aniline by laser photolysis, an importance being attached to the effect of the alkoxyl substituent on the reactive position. The nitro group enhances the substitution at the para position, but the alkoxyl group does not play a significant role in the photosubstitution of the molecules.
- 公益社団法人 日本化学会の論文
著者
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NAKAMURA Junko
The Institute of Physical and Chemical Research
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Mutai Kiyoshi
Department Of Chemistry Graduate School Of Arts And Sciences The University Of Tokyo
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Yokoyama Kenji
The Institute of Physical and Chemical Research
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Nagakura Saburo
The Institute for Molecular Science
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