Photoelectron angular distribution measurements for some aliphatic alcohols, amines, and halides.
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概要
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The angular distributions for the He I photoelectron spectra of some aliphatic alcohols, amines, and halides were measured in order to reexamine the assignments of the so-called p-type photoelectron spectral bands in the He I region of these molecules. The second band of methanol and the third band of ethanol were assigned to the in-plane n orbitals localized mainly on the oxygen atom. Furthermore, it was found that the angular distributions of photoelectrons were useful for the conformational analysis of molecules and that the sum of β values was conserved for these compounds.
- 公益社団法人 日本化学会の論文
著者
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Kobayashi Tsunetoshi
The Institute for Solid State Physics, The University of Tokyo
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Utsunomiya Chikatoshi
The Institute for Solid State Physics, The University of Tokyo
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Nagakura Saburo
The Institute for Molecular Science
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