Laser induced biphotonic dissociation of nitrobenzene derivatives in solution.
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By irradiation with a focused laser beam, <I>p</I>-nitroanisole and <I>N</I>-[2-(<I>p</I>-nitrophenoxy)ethyl] aniline (<B>2</B>) in acetonitrile were found to show new reactions yielding nitroso compounds different from the case of the defocused laser beam irradiation. The laser intensity dependence of the product yield shows that the new reaction of <B>2</B> proceeds <I>via</I> a biphotonic process. The quenching effects of oxygen and <I>cis</I>-1,3-pentadiene upon the reaction rate indicate that the intermediate state is an excited singlet state.
- 公益社団法人 日本化学会の論文
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