The photoreduction of viologen dyes with palladium meso-tetraphenylporphyrintrisulfonate.
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概要
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Pd–TPPS<SUB>3</SUB> was found to be an effective photosensitizer for the photoreduction of viologen dyes, such as methyl, ethyl, propyl, butyl, and heptyl viologens. The order of the reduction rate was as follows: Ethyl>Butyl>Methyl>Propyl>Heptyl. The respective complex formation was observed between Pd–TPPS<SUB>3</SUB> and viologen dyes, and electron transfer from photoexcited Pd–TPPS<SUB>3</SUB> to viologen dye was discussed.
- 公益社団法人 日本化学会の論文
著者
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Okura Ichiro
Department Of Bioengineering Tokyo Institute Of Technology
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Aono Shigetoshi
Department Of Bioengineering Tokyo Institute Of Technology
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Takeuchi Makoto
Department Of Biology Faculty Of Science Okayama University
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Kusunoki Shin
Department of Chemical Engineering, Tokyo Institute of Technology
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