Kinetics of the thermal decomposition of nickel sulfate.
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概要
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The rate of thermal decomposition of nickel sulfate was measured in the temperature range from 1003 K to 1078 K. When a powder sample was used, this reaction was characterized as a contracting volume reaction, with apparent activation energy of 296 kJ mol<SUP>−1</SUP>. The gaseous products were sulfur trioxide, sulfur dioxide, and oxygen. The composition of the gaseous products was near equilibrium in regard to the reaction, SO<SUB>3</SUB>=SO<SUB>2</SUB>+1/2 O<SUB>2</SUB>, because the nickel oxide formed had high catalytic activity for this reaction.
- 公益社団法人 日本化学会の論文
著者
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Onuki Kaoru
Japan Atomic Energy Agency
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IKEZOE Yasumasa
Japan Atomic Energy Research Institute
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SHIMIZU Saburo
Japan Atomic Energy Research Institute
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ONUKI Kaoru
Japan Atomic Energy Research Institute
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NAKAJIMA Hayato
Japan Atomic Energy Research Institute
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SATO Shoichi
Japan Atomic Energy Research Institute
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