Radiation Synthesis of Ethylamine from Ethane–Ammonia Systems. Effect of Nitric Oxide Addition
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概要
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Formation of ethylamine was observed in the γ-radiolysis of the ethane–ammonia system: the maximum <I>G</I> value was 0.5. Using oxygen as a radical scavenger, it was found that the ethylamine was formed <I>via</I> radical and ion intermediates. Addition of excess nitric oxide suppressed the ethylamine yield, but <I>G</I>(C<SUB>2</SUB>H<SUB>5</SUB>NH<SUB>2</SUB>) increased to 1.2 on addition of an optimum amount. This was attributed to the reduction of acetaldoxime by hydrogen atoms or alkyl radicals, after acetaldoxime had been formed by the reaction between ethyl radicals and the nitric oxide added as a scavenger.
- 公益社団法人 日本化学会の論文
著者
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IKEZOE Yasumasa
Japan Atomic Energy Research Institute
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SHIMIZU Saburo
Japan Atomic Energy Research Institute
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SATO Shoichi
Japan Atomic Energy Research Institute
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