Fission fragment radiolysis in ethane-ammonia system.
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概要
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Upon examining the effect of the presence of fission fragments (FF) on the formation by radiolysis of ethylamine and n-butane in ethane-ammonia system, no difference was discerned in the G-value, observed in the range of 114 kg/cm<SUP>2</SUP>, between radiation containing FF and others devoid of FF-mixed radiations from reactor and <SUP>60</SUP>Co γ-rays. This result would indicate that the predominant reaction in the core of FF track is proton transfer from positive ions to ammonia, as in the case of γ-radiolysis. Rising total pressure of the system was found to bring about a decrease in G(C<SUB>2</SUB>H<SUB>5</SUB>NH<SUB>2</SUB>) and an increase in G(n-C<SUB>4</SUB>H<SUB>10</SUB>). This behavior of the G-values indicates ionic formation of ethylamine by the reaction ;<BR>C<SUB>2</SUB>H<SUB>5</SUB><SUP>+</SUP>+NH<SUB>3</SUB>→C<SUB>2</SUB>H<SUB>5</SUB>NH<SUB>3</SUB>→<SUP>e<SUP>-</SUP></SUP>C<SUB>2</SUB>H<SUB>5</SUB>NH<SUB>2</SUB>+H.
- 一般社団法人 日本原子力学会の論文
著者
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IKEZOE Yasumasa
Japan Atomic Energy Research Institute
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SHIMIZU Saburo
Japan Atomic Energy Research Institute
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SATO Shoichi
Japan Atomic Energy Research Institute
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