Radiation chemical reactions in carbon dioxide-propane system. III. Formation of oxygen containing products.
スポンサーリンク
概要
- 論文の詳細を見る
The <I>G</I> value of water and 2-propanol as well as that of carbon monoxide decreased with decrease in propane concentration below 0.5%, the value of acetone remaining constant. Considering the effects of dose rate and irradiation temperature on the product yields, the results indicate that the formation of water and 2-propanol competes with the back reaction, or the reoxidation of carbon monoxide. A clustered negative ion, O<SUP>−</SUP>(CO<SUB>2</SUB>)<I><SUB>n</SUB></I> seems to be the oxidizing species responsible both for the back reaction and the formation of water and 2-propanol. The <I>G</I> value of O<SUP>−</SUP>(CO<SUB>2</SUB>)<I><SUB>n</SUB></I> was estimated to be 1.3. The formation of acetone is independent of the back reaction.
- 公益社団法人 日本化学会の論文
著者
-
IKEZOE Yasumasa
Japan Atomic Energy Research Institute
-
SATO Shoichi
Japan Atomic Energy Research Institute
関連論文
- Isotope Effect in the Photodissociation of Ammoniated Ammonium Ions by CO_2 Laser
- Ammoniated Ammonium Ions Studied Theoretically and Experimentally, ab initio Calculation and Tandem Mass Spectrometer Experiments
- Behavior of fission fragments released into chemical reactant from U-Pd alloy foil.
- Measurement of Absorbed Dose and Flux in a Reactor by Chemical Dosimetry
- Alanine Dosimetry of 14 MeV Neutrons in FNS Target Room
- Chemical dosimetry of mixed radiations in FNS target room.
- Radiation Synthesis of Hydrogen Cyanide from Nitrogen–Ethylene System. Effect of Temperature, Gas Density, and Reactor Wall
- Radiation Synthesis of Methylal from Methanol Solution of Ferric Chloride
- Radiation chemical reactions in carbon dioxide-propane system. Formation of carbon monoxide by fission fragments.:Formation of Carbon Monoxide by Fission Fragments
- The Radiation Synthesis of Hydrogen Cyanide from the Nitrogen–ethylene System. The Effect of Fission-fragment Irradiation
- Radiation chemical reactions in carbon dioxide-propane system. II. Reoxidation of carbon monoxide at low propane concentration.
- Radiation Synthesis of Ethylamine from Ethane–Ammonia Systems. Effect of Nitric Oxide Addition
- Fission fragment radiolysis in ethane-ammonia system.
- Kinetics of the thermal decomposition of nickel sulfate.
- A New Class of Thermochemical Hydrogen Production Processes
- Radiation chemical reactions in carbon dioxide-propane system. III. Formation of oxygen containing products.