The Radiation Synthesis of Hydrogen Cyanide from the Nitrogen–ethylene System. The Effect of Fission-fragment Irradiation
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概要
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Upon irradiation by (FF+n+γ), the <I>G</I>(HCN) value from the nitrogen-ethylene system increased with the rise in the pressure, while upon y and (n+γ) radiations it decreased. This pressure effect was explained in terms of the high concentration of the active species in the FF tracks. At a high pressure, Reaction (5) is considered to take place in the tracks;<BR>_2^++e^-→2N\tag5<BR>\intertextAt low pressures, Reaction (6) predominates, as in the γ-ray radiolysis, over Reaction (5) even in the FF tracks,<BR>_2^++C_2H_4→N_2+C_2H_4^+\tag6<BR>and nitrogen molecule cations do not contribute to the formation of hydrogen cyanide.
- 公益社団法人 日本化学会の論文
著者
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IKEZOE Yasumasa
Japan Atomic Energy Research Institute
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SATO Shoichi
Japan Atomic Energy Research Institute
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