Conversions of carbonyl compounds via their polymeric sulfonylhydrazones into alkenes, alkanes, and nitriles.
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概要
- 論文の詳細を見る
Reins consisting of cross-linked poly(styrene-divinylbenzene) matrices functionalized with hydrazinosulfonyl groups react with aldehydes and ketones to form the sulfonylhydrazone derivatives. The extent of the reaction is sensitive to the type of resin and the bulk of the carbonyl compound. When heated strongly under alkaline conditions, the sulfonylhydrazones release the corresponding alkenes; upon the NaBH<SUB>4</SUB> or LiAlH<SUB>4</SUB> treatment, they also release the corresponding alkanes; and, upon refluxing in methanol with potassium cyanide, they release nitriles containing one additional carbon atom.
- 公益社団法人 日本化学会の論文
著者
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NANASAWA Masato
Department of Applied Chemistry and Biotechnology, Yamanashi University
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Naito Takeshi
Department Of Applied Chemistry Tokyo University Of Science
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Kamogawa Hiroyoshi
Department of Applied Chemistry and Biotechnology, Faculty of Engineering, Yamanashi University
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Kanzawa Asami
Department of Applied Chemistry, Yamanashi University
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Kadoya Masahiro
Department of Applied Chemistry, Yamanashi University
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