Polymer reagents derived from sodium p-styrenesulfonate: N-methyl-N-nitroso-p-styrenesulfonamide and p-styrenesulfinic acid polymers.
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概要
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<I>N</I>-Methyl-<I>N</I>-nitroso-<I>p</I>-styrenesulfonamide (<B>1</B>) was synthesized starting with sodium <I>p</I>-styrenesulfonate (<B>3</B>). Monomer <B>1</B> and sodium <I>p</I>-styrenesulfinate (<B>2</B>), also synthesized starting with <B>3</B>, were polymerized and polymer of <B>2</B> was converted to corresponding free acid (<B>9</B>). The function of polymer of <B>1</B> as the reagent attaching the CH<SUB>2</SUB> group to the carbonyl carbon by insertion and that of polymer <B>9</B> as the catalyst for cis→trans isomerization were investigated for various compounds, including cyclohexanone and benzaldehyde and ethyl oleate. The effects of these polymer reagents as compared with those of the corresponding model compounds were discussed.
- 公益社団法人 日本化学会の論文
著者
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Kamogawa Hiroyoshi
Department of Applied Chemistry and Biotechnology, Faculty of Engineering, Yamanashi University
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Kitamura Tomoo
Department of Applied Chemistry, Yamanashi University
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