Halogenation of mixed ligand cobalt(III) complexes with 12- or 13-membered tetraaza macrocycle and acetylacetone, (Co(Z)aneN4(acac))(ClO4)2 (Z=12,13).
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概要
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The parent cobalt(III) complex [Co[12]aneN<SUB>4</SUB>(acac)](ClO<SUB>4</SUB>)<SUB>2</SUB>, [Co[12]aneN<SUB>4</SUB>(bzac)](ClO<SUB>4</SUB>)<SUB>2</SUB>, or [Co[13]aneN<SUB>4</SUB>(acac)](ClO<SUB>4</SUB>)<SUB>2</SUB> reacts with <I>N</I>-halogenosuccinimide to give the substituted complex [Co[12]aneN<SUB>4</SUB>(Xacac)(ClO<SUB>4</SUB>)<SUB>2</SUB>, [Co[12]aneN<SUB>4</SUB>(Xbzac)](ClO<SUB>4</SUB>)<SUB>2</SUB>, or [Co[13]aneN<SUB>4</SUB>-(Xacac)](ClO<SUB>4</SUB>)<SUB>2</SUB>, where [12]aneN<SUB>4</SUB>=1,4,7,10-tetraazacyclododecane, [13]aneN<SUB>4</SUB>=1,4,7,10-tetraazacyclotridecane, acac=acetylacetonato, bzac=benzoylacetonato, X=Cl, Br.
- 公益社団法人 日本化学会の論文
著者
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Hirano Akira
Department Of Chemistry And Materials Science Tokyo Institute Of Technology
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Ohyoshi Akira
Department Of Applied Chemistry Faculty Of Engineering Kumamoto University
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Matsumoto Naohide
Department of Applied Chemistry, Faculty of Engineering, Kumamoto University
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Matsumoto Naohide
Department of Industrial Chemistry Faculty of Engineering, Kumamoto University
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