Selective formation of solute radicals in the radiolysis of neopentane-cyclopentane mixtures at 4 and 77K as studied by capillary gas chromatography and ESR spectroscopy.
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概要
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The dimer yields in the radiolysis of the <I>neo</I>-C<SUB>5</SUB>H<SUB>12</SUB>-<I>cyclo</I>-C<SUB>5</SUB>H<SUB>10</SUB> (1 mol%) mixtures at 77 and 4 K have been measured by capillary gas chromatography. Analysis of the results indicates that cyclopentyl radicals are produced selectively at 77 K, while their selective formation is suppressed at 4 K. This result coincides well with the data obtained by ESR spectroscopy.
- 公益社団法人 日本化学会の論文
著者
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Miyazaki Tetsuo
Department Of Applied Chemistry Graduate School Of Engineering Nagoya University
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Fueki Kenji
Department of Chemistry Faculty of Science Osaka University
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Tilquin Bernard
Laboratoire de Chimie Inorganique et Analytique, Universite Catholique de Louvain
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Gourdin-Serveniere Catherine
Laboratoire de Chimie Inorganique et Analytique, Universite Catholique de Louvain
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