The reaction of (Z)-2-(3-oxo-1-propenyl)-2H-azirine derivative with molybdenum carbonyl complexes.
スポンサーリンク
概要
- 論文の詳細を見る
The thermal reaction of (<I>Z</I>)-2,3-diphenyl-2-(2,3-diphenyl-3-oxo-1-propenyl)-2<I>H</I>-azirine with [Mo(CO)<SUB>6</SUB>] or [Mo(CO)<SUB>3</SUB>(MeCN)<SUB>3</SUB>] was reinvestigated to afford 2,3,5,6-tetraphenylpyridine along with the pyrroles and 1,3-oxazepine derivative. The formation of 1,3-oxazepine was demonstrated to be the purely thermal process. The 1,2,4,5-tetraphenyl-5-oxo-1,3-pentadienylnitrene complex was shown to give the pyridine and the pyrrole derivatives.
- 公益社団法人 日本化学会の論文
著者
-
Nitta Makoto
Department Of Applied Pharmacology Toyama Medical And Pharmaceutical University
-
Kobayashi Tomoshige
Department Of Chemistry Faculty Of Science Shinshu University
関連論文
- Pharmacological and Immunohistochemical Characterization of a Mouse Model of Acute Herpetic Pain
- Roles of luteinizing hormone/chorionic gonadotropin receptor in anchorage-dependent and -independent growth in human ovarian surface epithelial cell lines
- Norbornadiene-Fused Heterocycles: Syntheses and Cycloaddition Reactions of 2-Aryl-4,7-dihydro-4,7-methano-2H-isoindoles and 4,7-Dihydro-4,7-methanoisobenzofuran
- Neighboring Group Participation by Heteroaromatic Rings : The Wagner-Meerwein Type Skeletal Rearrangement in the Electrophilic Addition Reactions of Norbornadiene-Fused Furans, Pyrroles, and Thiophenes
- Oxidizing Ability of a Series of (Tropon-2-ylimino)pnictoranes (Pnictogen=P, As, Sb, and Bi) toward Some Alcohols
- Synthesis and Properties of α, α-Bis(heteroazulen-3-yl)-1, 4-benzoquinonemethides
- The Effect of Fused Rings on the Spectral and Electrochemical Properties of Bis-Fused 1, 4-Diacetyl-1, 4-dihydropyrazines
- Norbornadiene-Fused Heterocycles : Synthesis of 5,8-Dihydro-5,8-methanophthalazines and Regioselective Ring Cleavage and Skeletal Rearrangement of 6,7-Epoxy-5,6,7,8-tetrahydro-5,8-methanophthalazine 2-Oxides in Trifluoroacetic Acid
- Norbornadiene-Fused Heterocycles : Synthesis and Bromination Reaction of 5,8-Dihydro-5,8-methanoquinoxaline Derivatives
- Cycloadditions of constrained dicyclopropylethylenes and divinylcyclopropanes with tetracyanoethylene.
- Preparation, 1,3-dipolar cycloaddition, and thermal and photochemical reactions of 3,5-exo- and 3,5-endo-7-methylene-4-azateracyclo[4.2.1.0.2,803,5]nona-9-ones.
- Thermal rearrangements of 1,5-dimethyl- and 1,3,5-trimethyl-8-vinyl-6-methylenetricyclo[3.2.1.02,7]oct-3-en-8-ol and their alkoxides.
- Hexacarbonylmolybdenum-induced N-N bond cleavage of pyrazoles. Conversion of 1-acylpyrazoles to pyrimidines.
- Acid-Induced Dimerization Reactions of N-(Diphenylphosphinyl)-2-propenimines Leading to Pyridine Derivatives.
- On the reaction of N-(diphenylphosphinyl)-1-phenylethanimine with aromatic aldehydes giving 4-aryl-2,6-diphenylpyridine derivatives.
- The solvomercuration, bromination, and related reactions of 1,5-dimethyl-6-methylenetricyclo(3.2.1.02,7)oct-3-en-8-one and its related compounds.
- On the reaction of N-vinyliminophosphoranes. 9. The synthesis and reaction of N-(1,3,5-cycloheptatrienyl)iminophosphoranes to provide a novel route to 1-azaazulenes.
- Preparation of novel N-vinyl-, N-(1-butylvinyl)-, and N-(1-methyl-1-pentenyl)iminotriphenylphosphoranes and their reactions with .ALPHA.,.BETA.-unsaturated ketones.
- The preparation and photoreation of spiro(oxirane-2,6'-tricyclo(3.2.1.02,7)oct(3)en)-8'-ones. An intramolecular cycloaddition of photochemically generated ketene with the epoxide ring.
- Photocycloadditions of benzophenone with 6-methylenetricyclo(3.2.1.02,7)oct-3-en-8-one and its related compounds. Di-.PI.-methane photorearrangement of the primary photocycloadducts.
- Stereoelectronic and homoconjugative effect of stereoselectivity. The addition of dichlorocarbene to 1,5-dimethyl-6-methylenetricyclo(3.2.1.02,7)oct-3-en-8-one and its related compounds.
- Nonacarbonyldiiron-, pentacarbonyliron-, or hexacarbonylmolybdenum-induced reacions of 4,5-polymethylene-substituted 2-isoxazolines.
- Metal carbonyl-induced N-O bond cleavage of the oxime group.
- Hexacarbonylmolybdenum-induced reaction of isoxazoles. Cycloaddition of isoxazoles with acetylenic esters and related reactions.
- Deoximation of oxime O-acetates, oximes, and oxime ethers by nonacarbonyldiiron or pentacarbonyliron. An electronic effect for the N-O bond cleavage.
- Synthesis and properties of the (n)(2,5)pyridinophane ring system.
- The reaction of (Z)-2-(3-oxo-1-propenyl)-2H-azirine derivative with molybdenum carbonyl complexes.
- On the reaction of N-vinyliminophosphoranes. Part 10. On the reaction of N-vinyliminophosphoranes with 2,4,6-cyclooctatrienone. Intermediate formation of 8-azabicyclo[5.3.1]undeca-2,4,7,9-tetraene ring system.
- The reaction of N-(vinylimino)phosphoranes. Part 13. On the reaction of N-(3-oxo-2-cyclohexenyl)imino)triphenylphosphorane with .ALPHA.-bromo ketones and .ALPHA.,.BETA.-unsaturated ketones.
- Nonacarbonyldiiron-induced reaction of 3-azido-1,2,3-triphenyl-cyclopropene and 4,5,6-triphenyl-1,2,3-triazine.
- A novel formation of phenyl-substituted pyridines by the reaction of N-(diphenylphosphinyl)-1-azaallyl anions with .ALPHA.,.BETA.-unsaturated carbonyl compounds. A new synthetic equivalent of primary vinylamines.