Hexacarbonylmolybdenum-induced N-N bond cleavage of pyrazoles. Conversion of 1-acylpyrazoles to pyrimidines.
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概要
- 論文の詳細を見る
[Mo(CO)<SUB>6</SUB>]-induced reactions of 1-acyl-3,5-disubstituted pyrazoles underwent N–N bond cleavage and subsequent cyclocondensation to give pyrimidines as well as deacylation to give 3,5-disubstituted pyrazoles. Under similar conditions, 1,3,5-trisubstituted pyrazoles, which have no electron-withdrawing substituent on N1, gave no product, except for the starting materials.
- 公益社団法人 日本化学会の論文
著者
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Nitta Makoto
Department Of Applied Pharmacology Toyama Medical And Pharmaceutical University
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Hamamatsu Tatsuo
Department of Chemistry, School of Science and Engineering, Waseda University
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Miyano Hiroyuki
Department of Chemistry, School of Science and Engineering, Waseda University
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