Studies of "manganese cycle" for gasification of solid carbon resources. I. Formation and hydrolysis of manganese carbides and their repetition.
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概要
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A new carbide method based on "Manganese Cycle" was studied in order to produce new fuel gas. This process consists of four steps; (i) carbide production from Mn<SUB>2</SUB>O<SUB>3</SUB> and solid carbon sources, (ii) fuel gas production by means of hydrolysis of the carbide, (iii) spontaneous oxidation of Mn(OH)<SUB>2</SUB> with air to Mn<SUB>2</SUB>O<SUB>3</SUB>, and (iv) regeneration of the carbide from Mn<SUB>2</SUB>O<SUB>3</SUB> and new carbon sources. In this process, manganese is used as a recyclable medium for gas production, and hydrogen and hydrocarbons (C<SUB>1</SUB>–C<SUB>5</SUB>) are obtained by hydrolysis. Carbon monoxide generated during the formation of the carbide is also utilizable. The addition of Li<SUB>2</SUB>CO<SUB>3</SUB> was effective for the carbide reproduction.
- 公益社団法人 日本化学会の論文
著者
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Uchida Hiroyuki
Department Of Applied Chemistry And Biotechnology Faculty Of Engineering Fukui University
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Iwahara Hiroyasu
Department of Environmental Chemistry and Technology, Faculty of Engineering, Tottori University
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Mizoguchi Satoshi
Department of Environmental Chemistry and Technology, Faculty of Engineering, Tottori University
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Uchida Hiroyuki
Department of Environmental Chemistry and Technology, Faculty of Engineering, Tottori University
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