Temperature effect on the rhodium-catalyzed direct synthesis of ethylene glycol from carbon monoxide and hydrogen in several solvents.
スポンサーリンク
概要
- 論文の詳細を見る
The Rh<SUB>4</SUB>(CO)<SUB>12</SUB>/<I>N</I>-methyl-2-pyrrolidone system is featured in that the rate of ethylene glycol (EG) formation is significantly accelerated with increasing reaction temperature. The turnover frequency of EG at 300 °C and 2000 kg/cm<SUP>2</SUP> (H<SUB>2</SUB>/CO=1) is about 2000 h<SUP>−1</SUP>. The Rh<SUB>4</SUB>(CO)<SUB>12</SUB>/tributylamine system also has a high catalytic activity at a high temperature.
- 公益社団法人 日本化学会の論文
著者
-
Murata Kazuhisa
National Inst. Advanced Industrial Sci. And Technol. Hiroshima Jpn
-
Kobayashi Toshiaki
National Food Research Institute Ministry Of Agriculture Forestry And Fisheries
-
Masuda Takashi
National Institute Of Advanced Industrial Science And Technology
-
Matsuda Akio
National Chemical Laboratory for Industry
-
Murata Kazuhisa
National Chemical Laboratory for Industry
関連論文
- Hydrotreatment of Jatropha Oil to Produce Green Diesel over Trifunctional Ni-Mo/SiO_2-Al_2O_3 Catalyst
- Carbonylation of formaldehyde with Carbon Monoxide over Cation-Exchange Resin Catalysts
- Catalytic Methanol Decomposition at Low Temperature over Pd Catalyst Derived from Mesoporous Silica Carried Pd-Hydrotalcite
- Synthesis of Highly Heat-Resistant Soluble Polymers through Hydrosilylation Polymerization between Octakis (hydridosilsesquioxane) and Diynes
- Neodymium-Catalyzed Dehydrogenative Condensation of Methylsilane and Ceramization on the Resulting Polymer
- Clarification of Green Tea Extract by Microfiltration and Ultrafiltration
- Usefulness of Soil p-Nitrophenyl Acetate Esterase Activity as a Tool to Monitor Biodegradation of Polybutylene Succinate (PBS) in Cultivated Soil
- Synthesis of Zr-grafted SBA-15 as an Effective Support for Cobalt Catalyst in Fischer-Tropsch Synthesis
- Dehydrogenation and Isomerization of Butane over Cr Catalysts Supported on H-SSZ-35 Type Zeolites
- Hydrocracking of Fischer-Tropsch Wax to Diesel-range Hydrocarbons over Bifunctional Catalysts Containing Pt and Polyoxocation-pillared Montmorillonite
- New Peroxo-polyoxometalates Pillared Hydrotalcite Catalyst for Propylene Epoxidation by Molecular Oxygen in Methanol
- Catalytic Oxidation of Cyclohexene by Molecular Oxygen over Isopolyoxometalates
- Synthesis and Catalytic Activity of Niobium-Containing Hexagonal Mesoporous Silica
- Synthesis of Poly(butylene succinate) and Poly(ethylene succinate) Including Diglycollate Moiety
- Formation of ρ-Aminostyrene Cyclic Tetramer
- Three-dimensional flow analysis of a mechanical bileaflet mitral prosthesis
- Applications of homogeneous water-gas shift reaction. IV. Hydrocarbonylation and dimerization of methyl acrylate with CO and H2O.
- Effect of Ru3(CO)12 and triisopropylphosphine on the catalytic activity of CO hydrogenation by Co2(CO)8.
- Pressure effect in syngas conversion to ethylene glycol. A behavior of rhodium-tributylphosphine-N-methylpyrrolidone system under 1000atm.
- A new aspect of the pressure effect in syngas conversion to ethylene glycol.
- Temperature effect on the rhodium-catalyzed direct synthesis of ethylene glycol from carbon monoxide and hydrogen in several solvents.
- Homogeneous hydroformylation of methyl acrylate catalyzed by Co2(CO)8-di(tertiary phosphine) complexes.
- Applications of homogeneous water-gas-shift reaction. I. Further studies of the hydroformylation of propene with CO and H2O.
- Homogeneous hydrogenation of .ALPHA.,.BETA.-unsaturated ketones and aldehydes catalyzed by Co2(CO)8-di(tertiary phosphine) complexes.
- Applications of homogeneous water-gas shift reaction. III. A further study of the hydrocarbonylation. A highly selective formation of diethyl ketone from ethene, CO, and H2O.
- The Cobalt Carbonyl-catalyzed Hydroesterification of Butadiene with Carbon Monoxide and Methanol
- Cobalt-catalyzed hydrohydroxymethylation of formaldehyde: Effect of Ru3(CO)12 and phenol.
- Applications of homogeneous water-gas-shift reaction. II. The formation of dipropyl ketones as primary products from CO and H2O in the presence of an excess amount of propene. Cobalt-based catalytic hydrocarbonylation.
- A new catalyst for the low temperature oxo process with the characteristic of easy separation.
- Cobalt-catalyzed hydroesterification of formaldehyde dialkyl acetals.