Cobalt-catalyzed hydrohydroxymethylation of formaldehyde: Effect of Ru3(CO)12 and phenol.

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A catalyst system, containing Co<SUB>2</SUB>(CO)<SUB>8</SUB>, Ru<SUB>3</SUB>(CO)<SUB>12</SUB>, and phenol, was found to be effective for the hydrohydroxymethylation of formaldehyde to give ethylene glycol with the yield of ca.65%, better than those previously reported.
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