Pressure effect in syngas conversion to ethylene glycol. A behavior of rhodium-tributylphosphine-N-methylpyrrolidone system under 1000atm.
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概要
- 論文の詳細を見る
In syngas (CO+H<SUB>2</SUB>) conversion to ethylene glycol (EG), rhodium catalyst modified by tributylphosphine (P<I><SUP>n</SUP></I>Bu<SUB>3</SUB>) was found to be ca. 20 times more active under 1000 atm at 210 °C than under 500 atm. This unusual pressure effect was discussed on the basis of IR spectral data.
- 公益社団法人 日本化学会の論文
著者
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Wada Keisuke
Research Center Mitsubishi Kasei Corporation
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Murata Kazuhisa
National Inst. Advanced Industrial Sci. And Technol. Hiroshima Jpn
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Masuda Takashi
National Institute Of Advanced Industrial Science And Technology
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Matsuda Akio
National Chemical Laboratory for Industry
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Watanabe Eiichi
Research Center, Mitsubishi Chemical Industries Limited
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Murata Kazuhisa
National Chemical Laboratory for Industry
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Wada Keisuke
Research Center, Mitsubishi Chemical Industries Limited
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Masuda Takashi
National Chemical Laboratory for Industry
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