Electrical double layer formed on the monolayer of crown ether compounds.

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概要

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• The binding behavior of metal ions to the monolayers of a crown ether compound has been studied by the surface potential measurements. The obtained data are analyzed from the viewpoint of interfacial electrochemistry, i.e., the electrical double layer theory at the interfaces. The analysis reveals that the generated double layer at a membrane–solution interface after the complexing of metal ions with crown ethers is well described by the Stern model for the electrical double layer; it shows that there exists a possibility to evaluate the binding constants of metal ions with crown ethers under interfacial circumstances.

• 公益社団法人 日本化学会の論文

著者

• Matsumura Hideo

  Electrotechnical Laboratory Aist Miti

• Furusawa Kunio

  Department Of Chemistry Tukuba University

• Watanabe Tsutomu

  Department Of Applied Physics Faculty Of Engineering The University Of Tokyo

• Inokuma Seiichi

  Faculty of Engineering, Gunma University

• Inokuma Seiichi

  Faculty of Technology, Gunma University

• Kuwamura Tsunehiko

  Faculty of Technology, Gunma University

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