Chemical behavior of an oxygen ligand in the reaction between oxo complex of RuIV and alcohols to give both hydroxo and alkoxo complexes of RuIII.

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概要

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• Under mild conditions, <I>trans</I>-[RuCl(O)(py)<SUB>4</SUB>]<SUP>+</SUP> in alcohols changes to an alkoxo complex, <I>trans</I>-[RuCl(OR)(py)<SUB>4</SUB>]<SUP>+</SUP>, The hydroxo complex, <I>trans</I>-[RuCl(OH)(py)<SUB>4</SUB>]<SUP>+</SUP>, which retains the reactive oxygen of the oxo complex, was found to exist as a precursor in the formation of the alkoxo complex. The reaction progress was traced by spectrometrical and <SUP>18</SUP>O-labelling experiments.

• 公益社団法人 日本化学会の論文

著者

• MUKAIDA Masao

  Department of Chemistry, Faculty of Science and Engineering, Sophia University

• Howell F.

  Department Of Chemistry Faculty Of Science And Engineering Sophia University

• Nagao Hirotaka

  Department Of Chemistry Faculty Of Science And Engineering Sophia University

• Kakihana Hidetake

  Department Of Chemistry Sophia University

• Yukawa Yasuhiko

  Department Of Environmental Acience Faculty Of Science Niigata University

• Howell F.

  Department of Chemistry, Faculty of Science and Technology, Sophia University

• Aoyagi Kimitake

  Department of Chemistry, Faculty of Science and Technology, Sophia University

• Yukawa Yasuhiko

  Department of Chemistry, Faculty of Science and Technology, Sophia University

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