The formation of the N-bound hydroxyiminoacetylacetonato ligand by the reaction of nitrosyl in bis(2,2'-bipyridine)chloronitrosylruthenium(II) with acetylacetone.

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概要

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• Nitrosyl in [RuCl(bpy)<SUB>2</SUB>NO]<SUP>2+</SUP> reacts with Hacac, giving the N-bound hydroxyiminoacetylacetonato ligand(hia, CH<SUB>3</SUB>COC(NO)COCH<SUB>3</SUB><SUP>−</SUP>) under mild conditions. The reaction product, [Ru(hia)(bpy)<SUB>2</SUB>(H<SUB>2</SUB>O)]X (X=ClO<SUB>4</SUB>, PF<SUB>6</SUB>), was characterized on the basis of its IR spectra, including those of the <SUP>15</SUP><I>N</I>-complex.

• 公益社団法人 日本化学会の論文

著者

• MUKAIDA Masao

  Department of Chemistry, Faculty of Science and Engineering, Sophia University

• Mukaida Masao

  Department of Chemistry, Faculty of Science and Technology, Sophia University

• Nomura Terunosuke

  Department of Chemistry, Faculty of Science and Technology, Sophia University

• Yoneda Masakazu

  Department of Chemistry, Faculty of Science and Technology, Sophia University

関連論文

• Reductions of {RuNO}^6-Type Nitrosyls. Characteristics of the Two-Electron Reduction Species Isolated as a Complex Having a Formally Negatively Charged μ-Nitrosyl({RuNO}^8-{RuNO}^8) and the One-Electron Reduction Species Generated Electrochamically({RuNO}
• Synthesis and Electrochemical Behavior of the Complex Having μ_2-Nitrosyl Moiety, as a Two-Electron Reduction Species of a {RuNO}^6-Type Nitrosyl,[{Ru(μ_2-NO)}_2(2,2-bipy)_4]^
• An Important Role of the One-Electron Reduction Nitrosyl Coordinated to Ruthenium. A Redox-Induced Oxygen Atom Transfer Reaction between the Nitrosyl and Adjacent Nitrite Moieties of {RuNO}^7-Type Nitrosyl Complex
• Some Mechanistic Evidence for an Oxygen Transfer Reaction Accompanied by the Redox-Induced Nitrito-Nitro Linkage Isomerization of Ruthenium Complex Having Nitrosyl, cis-[Ru(NO)(X)(bpy)_2]^(X=ONO, NO_2)
• Different Electrochemical Behavior of Complexes Having the Identical Nitroso Ligand in cis-[Ru(N,O-hia)(bpy)_2]^+ and cis-[Ru(N,O-hia)(bpy)(py)_2]^+ (hia : Hydroxyiminoacetylacetonato, CH_3COC(NO)COCH_3￣)
• Successive Chemical Reactions Accompanying a One-Electron Oxidation of a {MNO}^6-Type Nitrosyl Complex, Pentachloro(nitrosyl)ruthenate(2-), and a Characterization of the Product Species
• Crystal Structure and Electrochemical Behavior of an Unusual Nitrosyl-Ru Complex Obtained by a Reaction of Ru_2(Me COO)_4 Cl with 2-Pyridinecarboxylic Acid
• Chemical behavior of an oxygen ligand in the reaction between oxo complex of RuIV and alcohols to give both hydroxo and alkoxo complexes of RuIII.
• Syntheses of Trinuclear Riitheniiim(III) Complexes with Dichloroacetato Ligands
• Syntheses of Formato-, Acetato-, Benzoato-, and Chlorosubstituted Acetatoruthenium Complexes, and Their Properties
• Ruthenium Complexes with Coordinated Hydroxyiminoacetylacetonato or Bridging Nitrosyl Groups Formed by the Reactions of Nitrosylruthenium(III) with Acetylacetone
• The Ruthenium Complexes Formed by the Reactions of Nitrosylruthenium(III) with Tin(II) in Hydrochloric Acid Solution
• The crystal structure of tetra-.MU.-acetato-diruthenium chloride.
• Structure of tetra-.MU.-formatodiruthenium bromide.
• The formation of the N-bound hydroxyiminoacetylacetonato ligand by the reaction of nitrosyl in bis(2,2'-bipyridine)chloronitrosylruthenium(II) with acetylacetone.

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