The Ruthenium Complexes Formed by the Reactions of Nitrosylruthenium(III) with Tin(II) in Hydrochloric Acid Solution
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概要
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The complexes formed by the reactions of nitrosylrutheniurn(III) in hydrochloric acid solutions with tin(II) chloride were investigated. The following reaction products, (Me<SUB>4</SUB>N)<SUB>2</SUB>[RuCl<SUB>3</SUB>(SnCl<SUB>3</SUB>)<SUB>2</SUB>-NO], [1]; (Me<SUB>4</SUB>N)<SUB>4</SUB>[RuCl<SUB>6</SUB>(SnCl<SUB>3</SUB>)<SUB>2</SUB>(NO)<SUB>2</SUB>]·H<SUB>2</SUB>O, [2]; (Me<SUB>4</SUB>N)<SUB>4</SUB>[RuCl(SnCl<SUB>3</SUB>)<SUB>5</SUB>], [3] and K<SUB>3</SUB>[Ru<SUB>2</SUB>-Cl<SUB>8</SUB>(H<SUB>2</SUB>O)<SUB>2</SUB>N], [4] were isolated as crystals and were characterized. On the basis of chemical and thermal analyses, and on the basis of observations of the magnetic properties, the conductivities, and the infrared spectra, it was concluded that complexes [1], [2], and [3] contain terminal or bridging nitrosyl groups and/or a coordinating SnCl<SUB>3</SUB><SUP>−</SUP> group, and that complex [4] contains a bridging nitrido group. The presence of the binuclear complex, "K<SUB>3</SUB>[Ru<SUB>2</SUB>Cl<SUB>9</SUB>(NO)<SUB>2</SUB>]," which has both the terminal and singly-bridged nitrosyl groups was also suggested. The relations among those complexes were discussed.
- 公益社団法人 日本化学会の論文
著者
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MUKAIDA Masao
Department of Chemistry, Faculty of Science and Engineering, Sophia University
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Mukaida Masao
Department of Chemistry, Faculty of Science and Technology, Sophia University
関連論文
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- Chemical behavior of an oxygen ligand in the reaction between oxo complex of RuIV and alcohols to give both hydroxo and alkoxo complexes of RuIII.
- Syntheses of Trinuclear Riitheniiim(III) Complexes with Dichloroacetato Ligands
- Syntheses of Formato-, Acetato-, Benzoato-, and Chlorosubstituted Acetatoruthenium Complexes, and Their Properties
- Ruthenium Complexes with Coordinated Hydroxyiminoacetylacetonato or Bridging Nitrosyl Groups Formed by the Reactions of Nitrosylruthenium(III) with Acetylacetone
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