Radical cyclization to seleno-substituted thiahomoprotoadamantanone and its unexpected conversion to the vinyl selenide.

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概要

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• Heating <I>Se</I>-phenyl bicyclo[3.3.1]non-6-ene-3-(selenothioperoxy)carboxylate with AIBN gives 5-phenyl-seleno-3-thia-2-homoprotoadamantan-2-one which is unexpectedly converted to the vinyl selenide via the selenoxide by oxidation with hydrogen peroxide or <I>m</I>CPBA.

著者

• Toru Takeshi

  Department Of Applied Chemistry Graduate School Of Engineering Nagoya Institute Of Technology

• Eguchi Shoji

  Institute Of Applied Organic Chemistry Faculty Of Engineering Nagoya University

• Maekawa Eturo

  Department Of Applied Chemistry Nagoya Institute Of Technology

• Ueno Yoshio

  Department Of Applied Chemistry Nagoya Institute Of Technology

• Kondo Kazumoto

  Institute of Applied Organic Chemistry, Faculty of Engineering, Nagoya University

• Kanefusa Toshiya

  Department of Applied Chemistry, Faculty of Engineering, Nagoya Institute of Technology

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