Selenation of 1,5-Naphthoquinones:Novel Synthesis of Naphthopyridoselenazines.
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概要
- 論文の詳細を見る
Selenation of 2-chloro- and 2,6-dichloro-1,5-naphthoquinones with benzeneselenolate ion, generated from diphenyl diselenide and tributylphosphine in an alkaline medium, afforded 2-phenylseleno- and 2,6-bis(phenylseleno)-1,5-naphthoquinones in excellent yields. Reaction of halo-1,4-naphthoquinones with 3-amino-2-pyridineselenolate ion generated from bis(3-amino-2-pyridyl) diselenide gave naphtho[2,1-<I>b</I>]pyrido[3,2-<I>e</I>][1,4]selenazines and pyrido[2,3-<I>b</I>]pyrido[3″,2″:5′,6′][1,4]selenazino[2′,3′:3,4]naphtho[1,2-<I>e</I>][1,4]selenazines in high yields.
- 公益社団法人 日本化学会の論文
著者
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Toru Takeshi
Department Of Applied Chemistry Graduate School Of Engineering Nagoya Institute Of Technology
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Watanabe Yoshihiko
Department Of Anesthesia Tokyo Metropolitan Hiroo General Hospital
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Sakakibara Makoto
Department Of Internal Medicine Yatsu Hoken Hospital
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Ishida Tetsuya
Department Of Anatomy Kagawa Medical University
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Ueno Yoshio
Department Of Applied Chemistry Nagoya Institute Of Technology
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Watanabe Yoshihiko
Department of Applied Chemistry, Nagoya Institute of Technology
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