Novel synthesis of carbamic ester from carbon dioxide, amine, and ortho ester.
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概要
- 論文の詳細を見る
Carbon dioxide reacted with aliphatic amines and ortho esters to form carbamic esters in good yields. The influence of different ortho esters on the carbamate synthetic reaction is described. In the case of orthocarbonates, carbamic esters were obtained in high yields. The reaction of carbon dioxide, amines, and ortho esters may involve a competitive reaction between the esterification of carbamic acid produced by a reaction of carbon dioxide with amine, and the alkylation of amine.
- 公益社団法人 日本化学会の論文
著者
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Ishii Shigeru
Department Of Applied Chemistry Faculty Of Engineering Toyo University
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Yoshida Yasuhiko
Department Of Applied Chemistry Faculty Of Engineering Toyo University
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Yamashita Tadataka
Department Of Applied Chemistry Faculty Of Engineering Toyo University
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Nakayama Hidenobu
Department of Applied Chemistry, Faculty of Engineering, Toyo University
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