Application of the SPE method to organic electrochemistry-X. Behaviors of the manganese redox couple incorporated in Pt-nafion and their mediatory oxidation of cinnamyl alcohol to cinnamaldehyde.
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概要
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The electrochemical behavior of a manganese redox couple incorporated into an SPE (Solid Polymer Electrolyte) composite electrode using Nafion (Pt–Nafion) was examined as a mediator for electroorganic syntheses. The mediatory reaction of the redox couple was examined in the oxidation of cinnamyl alcohol. The oxidation proceeded smoothly and gave cinnamaldehyde in high selectivity; the current efficiency was as high as 85%. The dissolving-out of manganese from the SPE was suppressed by the addition of 0.025 mol dm<SUP>−3</SUP> MnSO<SUB>4</SUB> to the catholyte.
- 公益社団法人 日本化学会の論文
著者
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Ogumi Zempachi
Department Of Energy & Hydrocarbon Chemistry Graduate School Of Engineering Kyoto University
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Takehara Zen-ichiro
Department Of Chemical Engineering Faculty Of Engineering Kansai University
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Zhen Chen
Department of Industrial Chemistry, Faculty of Engineering, Kyoto University
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Mizoe Toshiyuki
Department of Industrial Chemistry, Faculty of Engineering, Kyoto University
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