The thermal decomposition of ammonium zinc trihydrogenbis-(phosphate) monohydrate (NH4)ZnH3(PO4)2H2O.
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概要
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(NH<SUB>4</SUB>)ZnH<SUB>3</SUB>(PO<SUB>4</SUB>)<SUB>2</SUB>·H<SUB>2</SUB>O[NZHP] was prepared by a wet method. NZHP was gradually decomposed to di-(P<SUB>2</SUB>) and oligophosphates (<I>n</I>=3–9: P<SUB>oligo</SUB>). A part of the formation of P<SUB>oligo</SUB> involved hydrolysis of the –P–O–P– linkages of P<SUB>2</SUB>, which was accerelated by humidity. γ-Zn<SUB>2</SUB>P<SUB>2</SUB>O<SUB>7</SUB> partially crystallized from P<SUB>2</SUB>. Above 350°C, NZHP was changed to long-chain β-Zn(PO<SUB>3</SUB>)<SUB>2</SUB>.
- 公益社団法人 日本化学会の論文
著者
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NARIAI Hiroyuki
Department of Chemical Science and Engineering, Faculty of Engineering, Kobe University
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MOTOOKA Itaru
Department of Chemical Science and Engineering, Faculty of Engineering, Kobe University
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Takenaka Atsushi
Department Of Urology Hyogo Medical Center For Adults
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Kimura Koji
Department Of Animal Breeding And Reproduction National Institute Of Livestock And Grassland Science
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Kimura Koji
Department of Industrial Chemistry, Yonago National College of Technology
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Hieda Tsuyoshi
Department of Industrial Chemistry, Yonago National College of Technology
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Takenaka Atsushi
Department of Industrial Chemistry, Yonago National College of Technology
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