Studies on fused pyrimidine derivatives. Part IX. Thermal reactions of 6-methyl-5-((substituted hydrazono)methyl)-2,4(1H,3H)-pyrimidinediones with electron-deficient olefins and acetyle ne.
スポンサーリンク
概要
- 論文の詳細を見る
The thermal reactions of some 6-methyl-5-[(substituted hydrazino)methyl]-2,4(1<I>H</I>,3<I>H</I>)-pyrimidinediones (<B>1</B>) were investigated. The 1,5-hydrogen shift in <B>1</B> gave 5,6-dihydro-5,6-bis(methylene)-2,4(1<I>H</I>,3<I>H</I>)-pyrimidinedione intermediates, while the 1,2-hydrogen shift in <B>1</B> gave azomethine imine intermediates. These reaction profiles depend on the substituents of hydrazone moieties.
- 公益社団法人 日本化学会の論文
著者
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NOGUCHI Michihiko
Department of Applied Chemistry and Chemical Engineering
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Kajigaeshi Shoji
Department Of Applied Chemistry And Chemical Engineering Faculty Of Engineering Yamaguchi University
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Tsuruoka Takashi
Department of Industrial Chemistry, Faculty of Engineering, Yamaguchi University
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Tsuruoka Takashi
Department of Cardiology, Kita Medical Association Hospital
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Kiriki Yasutoshi
Department of Industrial Chemistry, Faculty of Engineering, Yamaguchi University
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Mizui Takahiro
Department of Industrial Chemistry, Faculty of Engineering, Yamaguchi University
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