Oxidation using quaternary ammonium polyhalides. V. Selective oxidation of benzyl alcohols by the use of benzyltrimethylammonium tribromide.
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概要
- 論文の詳細を見る
The reaction of several substituted benzyl alcohols with 1 equiv of benzyltrimethylammonium tribromide (BTMA Br<SUB>3</SUB>) in carbon tetrachloride under basic or neutral conditions gave the corresponding benzaldehydes, and with 2 equiv of BTMA Br<SUB>3</SUB> in aqueous alkaline solution and subsequent acid hydrolysis gave the corresponding benzoic acids, respectively, in satisfactory yields.
- 公益社団法人 日本化学会の論文
著者
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KAKINAMI Takaaki
Department of Chemical and Biological Engineering, Ube Technical College
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Okamoto Tsuyoshi
Department Of Applied Chemistry Faculty Of Engineering Osaka Univetsity
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Kajigaeshi Shoji
Department Of Applied Chemistry And Chemical Engineering Faculty Of Engineering Yamaguchi University
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Okamoto Tsuyoshi
Department of Industrial Chemistry, Ube Technical College
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Uesugi Takeshi
Department of Industrial Chemistry, Ube Technical College
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Utsunomiya Tomohisa
Department of Industrial Chemistry, Ube Technical College
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