A study of the reduction of chelated palladium on mercury electrode.
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概要
- 論文の詳細を見る
This paper investigates the reduction kinetics and mechanism of Pd(II)–ethylenediamine with cyclic voltammetry and normal pulse polarography techniques. The results indicate that the reduction is an irreversible process. The major kinetic parameters and diffusion coefficients of Pd(II)–ethylenediamine and other Pd(II)–aliphatic diamine complexes are reported. The influences of concentrations, pH values, and ligand structures on the reduction of Pd(II) complex are also discussed. The electrochemical reaction orders with respect to ethylenediamine and Pd(II)–ethylenediamine are found to be 0 and 1, respectively and these reaction orders demonstrate an undissociated complex reduction mechanism. Finally the iodide effect on normal pulse polarography is studied. The increase in current when iodide is added implies that the reduction is via the outer sphere path way.
- 公益社団法人 日本化学会の論文
著者
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Wang Y.
Department of Chemical Engineering, National Tsing Hua University
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Lai C.
Department of Architecture, National Cheng-Kung University
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Wan C.
Department of Chemical Engineering, National Tsing Hua University
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- A study of the reduction of chelated palladium on mercury electrode.
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