Asymmetric Transformation of (RS)-1,2,3,4-Tetrahydro-3-isoquinolinecarboxylic Acid via Salt Formation with (1S)-10-Camphorsulfonic Acid.
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概要
- 論文の詳細を見る
Asymmetric transformation of (<I>RS</I>)-1,2,3,4-tetrahydro-3-isoquinolinecarboxylic acid [(<I>RS</I>)-TIC] by use of (1<I>S</I>)-10-camphorsulfonic acid [(<I>S</I>)-CS] as a resolving agent gave a salt of (<I>S</I>)-TIC with (<I>S</I>)-CS with 90% optical purity in hexanoic acid. The TIC obtained from the salt was purified to give optically pure (<I>S</I>)-TIC in 80% yield based on the starting (<I>RS</I>)-TIC.
- 公益社団法人 日本化学会の論文
著者
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Sakata Shinji
Faculty Of Pharmaceutical Sciences Teikyo University
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KUROKAWA Hidemoto
Faculty of Engineering and High Technology Research Center, Kansai University
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Shiraiwa Tadashi
Faculty Of Chemistry Materials And Bioengineering Kansai University
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Furukawa Tsuyoshi
Faculty of Engineering, Kansai University
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Tsuchida Tamotsu
Faculty of Engineering, Kansai University
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Sunami Michio
Faculty of Engineering, Kansai University
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Sakata Shinji
Faculty of Engineering, Kansai University
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