The carboxylation of active methylene compounds with carbon dioxide in the presence of diphenylcarbodiimide and potassium carbonate.
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概要
- 論文の詳細を見る
Active methylene compounds were effectively carboxylated with carbon dioxide in the presence of diphenylcarbodiimide (DPC) as a biotin model and potassium carbonate. Fluorene was carboxylated even under a nitrogen atmosphere in the presence of DPC, indicating that a carbonate ion was the carbon source. The reaction occurred even in the presence of water. It was considered that reaction intermediates are stable to water and that the concentration of the carbonate ion is important for carboxylation.
- 公益社団法人 日本化学会の論文
著者
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KARASU Masa
Department of Materials Science and Engineering, Faculty of Engineering, Yamagata University
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Tagaya Hideyuki
Department Of Applied Chemistry Faculty Of Engineering
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Hashimoto Kazumi
Department Of Anesthesiology And Intensive Care Medicine Graduate School Of Medical Science Kanazawa
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Chiba Koji
Department of Applied Chemistry, Faculty of Engineering, Yamagata University
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Hashimoto Kazumi
Department of Materials Science and Engineering, Faculty of Engineering, Yamagata University
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Ono Tsuyoyuki
Department of Materials Science and Engineering, Faculty of Engineering, Yamagata University
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Moriwaki Yasusi
Department of Materials Science and Engineering, Faculty of Engineering, Yamagata University
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Chiba Koji
Department of Apblied Chemistry, Faculty of Engineering, Yamagata University
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