Vibrational Spectra and Normal Coordinate Calculations of HgNH<SUB>2</SUB>Cl and HgNH<SUB>2</SUB>Br
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概要
- 論文の詳細を見る
Infrared spectra of HgNH<SUB>2</SUB>Cl and HgNH<SUB>2</SUB>Br and the Raman spectrum of HgNH<SUB>2</SUB>Cl have been measured in the region from 4000 cm<SUP>−1</SUP> to 30 cm<SUP>−1</SUP>. Effects of changing the X(X=Cl,Br) ion were observed mainly in N–H stretching bands and in lattice vibrations. Calculations of normal frequencies were carried out using a force field which includes inter-molecular forces. An assignment of the lattice vibrations was proposed and the force constants were also calculated. The force constants of the inter-molecular hydrogen bonds N–H···Cl and N–H···Br were obtained as 0.212 mdyn/Å and 0.142 mdyn/Å, respectively.
- 公益社団法人 日本化学会の論文
著者
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Takahashi Hiroaki
Department Of Biochemistry And Molecular Biology Graduate School Of Science And Engineering Saitama
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Niwa Kiyoshi
Department Of Surgery Sameshima Hospital
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Higasi Keniti
Department of Chemistry, School of Science and Engineering, Waseda University
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Kajiura Teruo
Japan Electron Optics Laboratory, Company
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Kajiura Teruo
Japan Electron Optics Laboratory Co. Ltd.
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Niwa Kiyoshi
Department of Chemistry, School of Science and Engineering, Waseda University
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